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Product name: high power/energy lithium ion battery cells, phosphate based

Material Safety Data Sheet
Section 1 - Product Identification
Product Name:
High Power/Energy Lithium Ion Battery Cells, Phosphate Based
Model: LFP123A; LFP18650P; LFP18650E; LFP26650P; LFP26650EV; LFP26650E
Product Use: Electrical
Chemical Family: Mixture
Synonyms: LFP Battery, Lithium Iron Phosphate Battery
Manufacturer: : K2 Energy Solutions
1125 American Pacific Dr, Suite C
Henderson, NV 89074
Phone Number: 702-478-3590
Fax: 702-558-0180
24-Hour Emergency:
Chemtrec: 800-424-9300
Section 2 - Composition and Ingredient Information

Common Chemical Name
Percent of
Classification and Hazard
Content (%)
Labelling
Material Safety Data Sheet
Under normal use, this battery is not expected to expose user to hazardous ingredients.
USA: This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA
Hazard Communication Standard requirement. The information contained in this Material Safety Data
Sheet contains valuable information critical to the safe handling and proper use of the product. This
MSDS should be retained and available for employees and other users of this product.
Canada: This is not a control ed product under WHMIS. This product meets the definition of a
“manufactured article” and is not subject to the regulations of the Hazardous Products Act.
Section 3 - Hazards Identification
Preparation Hazards and Classification:
Not dangerous with normal use. The materials within the
battery may only represent a hazard if the structural integrity of the battery is compromised. Do not
expose the batteries to fire or open flame. Do not mix batteries of varying sizes, chemistries, or types.
Do not short circuit, puncture, incinerate, crush, over-charge, over discharge, or expose the batteries to
temperatures above or below the declared limit. Damage to the batteries will result in the risk of fire or
explosion, which could release dangerous hydrogen fluoride gas and exposure to the ingredients
contained within or their combustion products could be harmful.
Appearance, Color, and Odor: Solid object, no odor.
Primary Route(s) of Exposure: Risk of exposure will only occur if the battery cell is mechanically,
thermally, or electrically damaged and the enclosure is compromised. If this occurs, exposure to
electrolyte solutions contained within the battery cell may occur by inhalation, eye contact, skin contact
and ingestion.
Potential Health Effects:
Inhalation: Inhalation of material from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of material from a sealed battery is not an expected route of
exposure. Swal owing mists from a ruptured battery may cause respiratory irritation,
chemical burns of the mouth and gastrointestinal tract irritation.
Skin: Contact between the battery and skin wil not cause any harm. Skin contact with
positive and negative terminals of high voltages may cause burns to the skin. Skin
contact with a ruptured battery can cause skin irritation.
Eye: Eye contact with the contents of a ruptured battery can cause severe irritation to
the eye.
Medical Conditions Aggravated by Exposure: Medical conditions related to potential exposure
modalities may be exacerbated by exposure to the materials.
Section 4 – First Aid Measures
Skin Contact:
Remove affected articles of clothing. Wash affected area with lukewarm water for at least
30 minutes. If irritation or pain persists, seek medical attention.
Eye Contact: Wash affected eye with lukewarm water for at least 30 minutes. Rinse with saline solution
if possible. Seek medical attention.
Inhalation: Move victim to fresh air and remove source of contamination from area. Seek medical
attention.
Ingestions: Drink plenty of water and induce vomiting. Seek medical attention immediately.
Material Safety Data Sheet
Caution: In all cases evacuate the contaminated area. If irritation persists, seek medical assistance at
once.
Section 5 - Fire Fighting Measures
Extinguishing Media:
Water, carbon dioxide, dry chemical powder and foam are most effective means
to extinguish a battery fire
Fire Fighting Procedure: Put on ful y protective gear, including self-contained positive pressure
breathing apparatus, goggles, fireproofing jacket and gloves. Caution is advised during application of
water because burning particles may be ejected from the fire.
Unusual Fire and Explosion Hazards: Exposing battery cell to excessive heat, fire or over voltage
condition may cause a leak, fire, hazardous vapors and hazardous decomposition products. Damaged or
opened cells or batteries can result in rapid heating and the release of flammable vapors and potentially
dangerous gases that may be heavier than air and could travel along the ground or be moved by
ventilation to an ignition source.
Section 6 - Accidental Release Measures
The material contained within the batteries cells is only expelled if the battery is damaged. Evacuate the
area. Wear protective clothing and glasses. Use a shovel and cover battery with sand or vermiculite,
place in an approved container and dispose in accordance with section 13.
Section 7 – Handling and Storage
Handling:
Do not expose battery or cell to extreme temperatures or fire. Do not disassemble, crush or
puncture battery. Do not overcharge or overdischarge the battery. Do not mix batteries of varying types
or sizes. Do not connect positive and negative terminals or place the batteries on conductive metal.
Storage: Insulate positive and negative terminals to avoid short circuit and ensure sufficient clearance
between batteries and other surfaces. Store in a dry, cool (below 30°C and above -10°C) and well
ventilated area and avoid fire, heat. Elevated temperatures can result in reduced battery life and venting
of flammable liquid and gases. Keep batteries away from strong oxidizers and acids.
Section 8 – Exposure Controls and Personal Protection
Respiratory Protection:
Not necessary under normal use. In case of battery or cell rupture, use a self
contained full face respiratory mask.
Eye Protection: Not necessary under normal use. Wear safety goggles if handling a ruptured or leaking
battery cell.
Hand Protection: Not necessary under normal use. Wear Viton rubber gloves if handling a ruptured or
leaking battery cell.
Skin Protection: Not necessary under normal use. Wear rubber apron and Viton rubber gloves if
handling a ruptured or leaking battery cell.
OSHA: Occupational Safety and Health Administration
PEL-TWA: Permissible Exposure Limits-Time Weighted Average Concentration
ACGIH: American Council of Government Industrial Hygienists
TLV-TWA: Threshold Limit Value-Time Weighted Average Concentration
Material Safety Data Sheet

Common Chemical
OSHA PEL-TWA
ACGIH (2010) TLV-TWA
Name/General Name
5.0 mg/m3 (respirable 2.0 mg/m3 (respirable fraction) fraction) Section 9 – Physical and Chemical Properties
Physical State:

Odor Type:
Appearance:
Odor Threshold:
Evaporative Rate:
(n-Butyl Acetate = 1)
Relative Density:
Auto Ignition Temperature
Boiling Point:
Flammability Limits (%):
Melting Point:
Vapor Pressure:
(mm Hg @ 20 C°)
Viscosity:
Vapor Density:
Oxidizing Properties:
Solubility in Water:
Flash Point and Method (C°): Not
Water/ Oil distribution
coefficient:

Section 10 – Stability and Reactivity
Stability:
Stable
Conditions to Avoid: Avoid exposing battery to high temperatures. Do not incinerate, deform, mutilate,
crush, pierce, short circuit or disassemble.
Materials to Avoid: Not Applicable
Hazardous Decomposition Products: Combustible vapors may be released if exposed to fire.
Possibility of Hazardous Reactions: Hydrogen fluoride gas may be produced in reaction with water.
Section 11 – Toxicological Information
Material Safety Data Sheet
Irritation: Risk of irritation only occurs if battery cells are mechanically, thermally or electrically
damaged and the enclosure is compromised.
Neurological Effects: No information is available at this time.
Sensitization: The nervous system and organs may be sensitized by exposure.
Teratogenicity: No information is available at this time.
Reproductive Toxicity: No information is available at this time.
Mutagenicity (Genetic Effects): No information is available at this time.
Toxicologically Synergistic Materials: No information is available at this time.
Section 12 – Ecological Information
Bioaccumulative potential:
Not available.
Persistence and degradability: Not available.
Mobility: Not available.
Ecotoxicity: Not available.
Other adverse effects: Not available.

Section 13 – Disposal Considerations
Waste Disposal Method:
Recycling is encouraged. Discharge batteries fully and cap terminals before
disposal. Dispose of in accordance with local, state and federal laws and regulations.
USA: Dispose of in accordance with local, state and federal laws and regulations.
Canada: Dispose of in accordance with local, state and federal laws and regulations.
EC: Dispose of in accordance with relevant EC Directives.

Section 14 – Transport Information
Hazardous Classifications:
Based on lithium content:
Small quantities of single lithium ion battery cells are exempted from Class 9. No class 9 marking, specification packaging, or Class 9 labels are required. Use lithium ion battery labels for transport of lithium ion batteries which are not assigned Class 9.
Use Class 9 Miscellaneous Dangerous Goods and UN Identification labels for transportation of lithium
ion batteries which are assigned Class 9. Refer to relevant transportation documents.
Lithium and lithium ion cells and batteries are regulated in the U.S. in accordance with Part 49 of the
Code of Federal Regulations, (49 CFR Sections 105-180) of the U.S. Hazardous Materials Regulations.
Section 15 – Regulatory Information
USA

TSCA Status: Al ingredients in the product are listed on the TSCA inventory.
SARA Title III:
Material Safety Data Sheet
Sec. 302/304: None Sec. 311/312: None Sec. 313: None CERCLA RQ: None California Prop 65:
This product does not contain chemicals know to the State of California to cause cancer or reproductive
toxicity. [IS IT BETTER TO SAY “MAY CAUSE”]

Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains al the information required by the Control ed Products Regulations.
WHMIS Classification: Not Controlled
New Substance Notification Regulations: All ingredients in the product are listed, as required,
on Canada’s Domestic Substance List.
NPRI Substances (National Pollutant Release Inventory): This product does not contain any
NPRI chemicals.
EC Classification for the Substance/ Preparation:
Symbol: This product is not classified as dangerous according to Directive 1999/45/EC
and it’s amendments.
Risk Phrases: None
Safety Phrases: S2: Keep out of the reach of children.
Section 16 – Other Information
Preparation Date:
October 05, 2009
Revision Date: January 05, 2011
Revision Summary: B : Released.
Prepared by: K2 Energy Solutions
1125 American Pacific Dr, Suite C
Henderson, NV 89074
Phone: (702)478-3590
Disclaimer: The information and recommendations set forth are made in good faith and accurate at the
date of preparation. K2 Energy Solutions makes no warranty expressed or implied with respect to this
information and recommendations and disclaims all liability (including without limitation, all direct,
indirect, incidental, punitive or consequential liability) from reliance on it. The information relates to
specific materials designated and may not be valid for such materials used in combination with any
other materials or in any process. Each party using products and materials must determine the
suitability and completeness of this information for their intended use.

Source: http://www.acumentrics.com/Collateral/Documents/English-US/MSDS_Lithium-Ion-K2-Energy-Battery.pdf

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