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http://max.chemwatch.net/cg2/msds.exe?&mode=SAP&cwno=24-891.
CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL) Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME
STATEMENT OF HAZARDOUS NATURE
Conside re d a Hazardous Substance according to the crite ria of the Ne w Ze aland Hazardous Substance s Ne w Organisms le gislation.
PROPER SHIPPING NAME
PRODUCT USE
■ Application is by spray atomisation from a hand held aerosol pack. Used according to manufacturer's directions. Coating SUPPLIER
New ZealandTelephone: +64 9 272 2700Fax: +64 9 274 9696Email: customerservices@crc.co.nzWebsite: www.crc.co.nz CHEMWATCH HAZARD RATINGS
GHS Classification
Acute Aquatic Hazard Category 2
Acute Toxicity (Oral) Category 4
Eye Irritation Category 2A
Reproductive Toxicity Category 2Skin Corrosion/Irritation Category 2STOT - RE Category 2STOT - SE (Resp. Irr.) Category 3 EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.1D 6.3A 6.4A 6.8B 6.9 6.9B
Harmful if swallowedCauses skin irritationCauses serious eye irritationSuspected of damaging the unborn childMay cause respiratory irritationMay cause damage to organs through prolonged or repeated exposure by inhalation.
PRECAUTIONARY STATEMENTS
http://max.chemwatch.net/cg2/msds.exe?&mode=SAP&cwno=24-891.
CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL) Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash . thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
Response
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
Call a POISON CENTER or doctor/physician if you feel unwell.
Get medical advice/attention if you feel unwell.
Rinse mouth.
If eye irritation persists: Get medical advice/attention.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 50 oC/ 122 oF.
Disposal
Dispose of contents/container to .
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766) NZ EMERGENCY SERVICES: 111 SWALLOWED

Avoid giving milk or oils.
Avoid giving alcohol.
Not considered a normal route of entry.
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration ofvomitus.
EYE
■ If aerosols come in contact with the eyes:
Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper andlower lids.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
■ If solids or aerosol mists are deposited upon the skin:
Flush skin and hair with running water (and soap if available).
Remove any adhering solids with industrial skin cleansing cream.
DO NOT use solvents.
Seek medical attention in the event of irritation.
INHALED
■ If aerosols, fumes or combustion products are inhaled:
Remove to fresh air.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valvemask device, or pocket mask as trained. Perform CPR if necessary.
http://max.chemwatch.net/cg2/msds.exe?&mode=SAP&cwno=24-891.
CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL) NOTES TO PHYSICIAN
■ Treat symptomatically.
For acute or short term repeated exposures to acetone:
Symptoms of acetone exposure approximate ethanol intoxication.
About 20% is expired by the lungs and the rest is metabolised. Alveolar air half-life is about 4 hours following two hour inhalation at levels nearthe Exposure Standard; in overdose, saturable metabolism and limited clearance, prolong the elimination half-life to 25-30 hours.
There are no known antidotes and treatment should involve the usual methods of decontamination followed by supportive care.
[Ellenhorn and Barceloux: Medical Toxicology] Management:Measurement of serum and urine acetone concentrations may be useful to monitor the severity of ingestion or inhalation.
Inhalation Management: Maintain a clear airway, give humidified oxygen and ventilate if necessary.
If respiratory irritation occurs, assess respiratory function and, if necessary, perform chest X-rays to check for chemical pneumonitis.
Consider the use of steroids to reduce the inflammatory response.
Treat pulmonary oedema with PEEP or CPAP ventilation.
Remove any remaining contaminated clothing, place in double sealed, clear bags, label and store in secure area away from patients and staff.
Irrigate with copious amounts of water.
An emollient may be required.
Irrigate thoroughly with running water or saline for 15 minutes.
Stain with fluorescein and refer to an ophthalmologist if there is any uptake of the stain.
No GASTRIC LAVAGE OR EMETICEncourage oral fluids.
Monitor blood glucose and arterial pH.
Ventilate if respiratory depression occurs.
If patient unconscious, monitor renal function.
Symptomatic and supportive care.
The Chemical Incident Management Handbook:Guy's and St. Thomas' Hospital Trust, 2000 These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV): NS: Non-specific determinant; also observed after exposure to other material.
Following acute or short term repeated exposures to toluene: Toluene is absorbed across the alveolar barrier, the blood/air mixture being 11.2/15.6 (at 37 degrees C.) The concentration of toluene, inexpired breath, is of the order of 18 ppm following sustained exposure to 100 ppm. The tissue/blood proportion is 1/3 except in adipose wherethe proportion is 8/10.
Metabolism by microsomal mono-oxygenation, results in the production of hippuric acid. This may be detected in the urine in amountsbetween 0.5 and 2.5 g/24 hr which represents, on average 0.8 gm/gm of creatinine. The biological half-life of hippuric acid is in the order of 1-2hours.
Primary threat to life from ingestion and/or inhalation is respiratory failure.
Patients should be quickly evaluated for signs of respiratory distress (eg cyanosis, tachypnoea, intercostal retraction, obtundation) and givenoxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 <50 mm Hg or pCO2 > 50 mm Hg) should be intubated.
Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial damage has beenreported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents,so that hyperventilation improves clearance.
A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence ofpneumothorax.
Epinephrine (adrenaline) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation tocatecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a secondchoice.
Lavage is indicated in patients who require decontamination; ensure use.
BIOLOGICAL EXPOSURE INDEX - BEIThese represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV): NS: Non-specific determinant; also observed after exposure to other materialB: Background levels occur in specimens collected from subjects NOT exposed.
EXTINGUISHING MEDIA
■ SMALL FIRE:
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CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL) FIRE FIGHTING

Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
If safe, switch off electrical equipment until vapour fire hazard removed.
Use water delivered as a fine spray to control fire and cool adjacent area.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD

Liquid and vapour are highly flammable.
Severe fire hazard when exposed to heat or flame.
Vapour forms an explosive mixture with air.
Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
Vapour may travel a considerable distance to source of ignition.
Heating may cause expansion or decomposition with violent container rupture.
Aerosol cans may explode on exposure to naked flames.
Rupturing containers may rocket and scatter burning materials.
Hazards may not be restricted to pressure effects.
May emit acrid, poisonous or corrosive fumes.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon monoxide (CO).
Combustible. Will burn if ignited, carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.
FIRE INCOMPATIBILITY

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Personal Protective Equipment
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Wear protective clothing, impervious gloves and safety glasses.
Shut off all possible sources of ignition and increase ventilation.
Wipe up.
If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.
DO NOT exert excessive pressure on valve; DO NOT attempt to operate damaged valve.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water coursesNo smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Water spray or fog may be used to disperse / absorb vapour.
Absorb or cover spill with sand, earth, inert materials or vermiculite.
If safe, damaged cans should be placed in a container outdoors, away from ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.
Collect residues and seal in labelled drums for disposal.
Remove leaking cylinders to a safe place if possible.
Release pressure under safe, controlled conditions by opening the valve.
PROTECTIVE ACTIONS FOR SPILL
http://max.chemwatch.net/cg2/msds.exe?&mode=SAP&cwno=24-891.
CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL) From US Emergency Response Guide 2000 Guide 126 http://max.chemwatch.net/cg2/msds.exe?&mode=SAP&cwno=24-891.
CRC(NZ) 2110 Etch It Aerosol
Hazard Alert Code:
(Chemwatch name: CRC(NZ) 2110 ETCH IT AEROSOL)

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